Characterization of [Fe(AMN3S3sarH)]3+ - a rigorously low-spin iron(II) complex

Sharrad, C. A. and Gahan, L. R. (2003) Characterization of [Fe(AMN3S3sarH)]3+ - a rigorously low-spin iron(II) complex. Polyhedron: 1982-2002. 21 Years of Polyhedron: a Celebration, 22 1: 45-61. doi:10.1016/S0277-5387(02)01259-7

Author Sharrad, C. A.
Gahan, L. R.
Title Characterization of [Fe(AMN3S3sarH)]3+ - a rigorously low-spin iron(II) complex
Journal name Polyhedron: 1982-2002. 21 Years of Polyhedron: a Celebration   Check publisher's open access policy
ISSN 0277-5387
Publication date 2003-01-01
Year available 2003
Sub-type Article (original research)
DOI 10.1016/S0277-5387(02)01259-7
Volume 22
Issue 1
Start page 45
End page 61
Total pages 17
Place of publication Oxford, UK
Publisher Pergamon-Elsevier
Collection year 2002
Language eng
Subject C1
250201 Transition Metal Chemistry
780103 Chemical sciences
Abstract The iron(II) complex [Fe(AMN(3)S(3)sarH)](ClO4)(3).3H(2)O (AMN(3)S(3)sarH = 8-ammonio-1-methyl-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane) has been synthesized and characterized by single crystal structure and spectroscopic methods. The Fe(II)-S(thiaether) bond lengths are short, indicative of a large degree of metal-ligand orbital mixing (pi-acceptor character) of the thiaether ligand. The complex is stable to metal centred oxidation. (C) 2002 Elsevier Science Ltd. All rights reserved.
Keyword Chemistry, Inorganic & Nuclear
Encapsulating Ligand
Hexa-amine Cages
Q-Index Code C1

Document type: Journal Article
Sub-type: Article (original research)
Collections: Excellence in Research Australia (ERA) - Collection
School of Chemistry and Molecular Biosciences
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Created: Tue, 14 Aug 2007, 17:30:31 EST