Free radical copolymerization of methyl methacrylate and allyl acetate Part 2 structure and properties

Hendrana, Sunit, Hill, David J. T., Perera, M. C. Senake and Pomery, Peter J. (2001) Free radical copolymerization of methyl methacrylate and allyl acetate Part 2 structure and properties. Polymer International, 50 6: 700-706. doi:10.1002/pi.687


Author Hendrana, Sunit
Hill, David J. T.
Perera, M. C. Senake
Pomery, Peter J.
Title Free radical copolymerization of methyl methacrylate and allyl acetate Part 2 structure and properties
Journal name Polymer International
ISSN 1097-8103; 0959-8103
Publication date 2001
Sub-type Article (original research)
DOI 10.1002/pi.687
Volume 50
Issue 6
Start page 700
End page 706
Total pages 7
Place of publication United Kingdom
Publisher John Wiley for Society of Chemical Industry
Collection year 2001
Language eng
Subject C1
250502 Physical Chemistry of Macromolecules
780103 Chemical sciences
Abstract The structure of the product from the free radical bulk copolymerization of methyl methacrylate (MMA) and allyl acetate (AAc) was investigated. The mole fraction of AAc plays an important role in the copolymerization of these two monomers. Molecular weight (MW) and molecular weight distribution (MWD) are completely altered when the feed composition is dominantly AAc. NMR spectroscopy confirmed the incorporation of AAc into the polymer. However, no allyl-allyl linkages were observed at low conversions. T-g was found to be affected by the incorporation of AAc into the polymer. (C) 2001 Society of Chemical Industry.
Keyword Polymer Science
Copolymerization
Allyl
Nmr
Gpc
Vinyl-acetate
Polymers
Substituents
Q-Index Code C1

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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Created: Tue, 14 Aug 2007, 15:28:11 EST