N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations

Zerk, Timothy J., Moore, Peter W., Williams, Craig M. and Bernhardt, Paul V. (2016) N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations. Chemical Communications, 52 67: 10301-10304. doi:10.1039/C6CC05440D


Author Zerk, Timothy J.
Moore, Peter W.
Williams, Craig M.
Bernhardt, Paul V.
Title N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations
Journal name Chemical Communications   Check publisher's open access policy
ISSN 1364-548X
1359-7345
Publication date 2016
Year available 2016
Sub-type Article (original research)
DOI 10.1039/C6CC05440D
Open Access Status Not Open Access
Volume 52
Issue 67
Start page 10301
End page 10304
Total pages 4
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Collection year 2017
Language eng
Formatted abstract
The redox and ligand exchange reactions of oxido-ruthenium complexes are central to the function of the Sharpless and Griffith–Ley one-step alcohol oxidation protocols. However, their mechanisms have not been elucidated. Cyclic voltammetry and UV-vis spectroelectrochemical analysis of [RuO4] has provided new insight into the key ruthenium oxidation states involved in catalysis. Furthermore, the oxidation states sensitive to the presence of the N-oxide co-oxidant N-methylmorpholine N-oxide (NMO), and its role in catalysis, have been determined.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: HERDC Pre-Audit
School of Chemistry and Molecular Biosciences
 
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Created: Fri, 05 Aug 2016, 10:35:11 EST by Mrs Louise Nimwegen on behalf of School of Chemistry & Molecular Biosciences