Electrochemical Properties and Discharge Kinetics of Thin Layer Hydrous Molybdenum Oxide

Elliott D. (1977) Electrochemical Properties and Discharge Kinetics of Thin Layer Hydrous Molybdenum Oxide. Journal of the Electrochemical Society, 124 8: 1243-1246. doi:10.1149/1.2133538


Author Elliott D.
Title Electrochemical Properties and Discharge Kinetics of Thin Layer Hydrous Molybdenum Oxide
Journal name Journal of the Electrochemical Society   Check publisher's open access policy
ISSN 1945-7111
Publication date 1977
Sub-type Article (original research)
DOI 10.1149/1.2133538
Volume 124
Issue 8
Start page 1243
End page 1246
Total pages 4
Subject 1603 Demography
3104 Condensed Matter Physics
2504 Electronic, Optical and Magnetic Materials
2505 Materials Chemistry
2105 Renewable Energy, Sustainability and the Environment
2508 Surfaces, Coatings and Films
3110 Surfaces and Interfaces
Abstract Thin layer hydrated molybdenum oxide (oxidation state IV or V) has been deposited electrochemically on a variety of substrates, e.g., polycrystalline tin oxide coated glass. It is capable of existing in an oxidized or reduced form and its equilibrium properties are described by a Nernst-like relationship. Experimentally the activities of the two forms are found to depend on a power function of their concentrations. The equilibrium position is also a function of pH. The rate of oxidation is described by a kinetic rate law of at least second order. Slow self-oxidation also occurs over a period of hours possibly due to the reduction of H+.
Keyword solid redox system
thin layer battery
thin layer capacitor
tin oxide
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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