Electrophilic substitution with allylic rearrangement (SE′). Syn-stereospecificity accompanying sulfur dioxide insertion into 4- and 6-alkylcyclohex-2-enyltrimethylstannanes

Young D. and Kitching W. (1983) Electrophilic substitution with allylic rearrangement (SE′). Syn-stereospecificity accompanying sulfur dioxide insertion into 4- and 6-alkylcyclohex-2-enyltrimethylstannanes. Tetrahedron Letters, 24 51: 5793-5796. doi:10.1016/S0040-4039(00)94203-5


Author Young D.
Kitching W.
Title Electrophilic substitution with allylic rearrangement (SE′). Syn-stereospecificity accompanying sulfur dioxide insertion into 4- and 6-alkylcyclohex-2-enyltrimethylstannanes
Journal name Tetrahedron Letters   Check publisher's open access policy
ISSN 0040-4039
Publication date 1983
Sub-type Article (original research)
DOI 10.1016/S0040-4039(00)94203-5
Volume 24
Issue 51
Start page 5793
End page 5796
Total pages 4
Subject 1303 Specialist Studies in Education
1605 Policy and Administration
3002 Drug Discovery
Abstract Sulfur dioxide insertion (chloroform solvent) into cis and trans-4 and -6-methyl- and 4-t-butylcyclohex-2-enyltrimethylstannanes is γ-regio and syn-stereospecific and hence less sensitive to steric effects by δ-substituents than trifluoroacetolysis (CF3COOD in CHCl3).
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 26 Jul 2016, 03:16:31 EST by System User