The acid-catalysed hydrolysis of α-methylallyl acetate in aqueous solution

Fredlein R.A. and Lauder I. (1968) The acid-catalysed hydrolysis of α-methylallyl acetate in aqueous solution. Australian Journal of Chemistry, 21 7: 1727-1731. doi:10.1071/CH9681727


Author Fredlein R.A.
Lauder I.
Title The acid-catalysed hydrolysis of α-methylallyl acetate in aqueous solution
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1968
Sub-type Article (original research)
DOI 10.1071/CH9681727
Volume 21
Issue 7
Start page 1727
End page 1731
Total pages 5
Subject 1600 Chemistry
Abstract The kinetics of the acid-catalysed hydrolysis of a-methylallyl acetate in aqueous solution have been studied over the range 30-100º. Oxygen-18 tracer experiments reveal the mechanism to be solely AAC2 and the Arrhenius parameters are consistent with this conclusion. Crotyl alcohol is observed in the reaction products. The formation of rearranged alcohol is explained by allylic isomerization of the α-methylallyl alcohol produced by the hydrolysis.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 26 Jul 2016, 02:55:01 EST by System User