Circular dichroism spectra of amino acid complexes. III.* Copper(II) compounds

Hawkins C.J. and Wong C.L. (1970) Circular dichroism spectra of amino acid complexes. III.* Copper(II) compounds. Australian Journal of Chemistry, 23 11: 2237-2246. doi:10.1071/CH9702237


Author Hawkins C.J.
Wong C.L.
Title Circular dichroism spectra of amino acid complexes. III.* Copper(II) compounds
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1970
Sub-type Article (original research)
DOI 10.1071/CH9702237
Volume 23
Issue 11
Start page 2237
End page 2246
Total pages 10
Subject 1600 Chemistry
Abstract The solution circular dichroism spectra of the 1: 1 and 1: 2 copper(II) complexes of a series of α-amino acids are reported for the region 12500-25000 cm-1. These spectra and spectra of the isolated 1: 2 complexes dispersed in KBr disks have been interpreted as arising from three Cotton effects with a -,+,- sign pattern for the L configuration, except for the L-proline spectra, which were analysed in terms of a +,-,+ pattern. A tentative assignment is made for these Cotton effects, and the relative contributions of vicinal and conformational effects to the rotational strength are discussed.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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