Structure of molten nitrates. I. estimation of effective interionic distances

James D.W. (1966) Structure of molten nitrates. I. estimation of effective interionic distances. Australian Journal of Chemistry, 19 6: 993-998. doi:10.1071/CH9660993


Author James D.W.
Title Structure of molten nitrates. I. estimation of effective interionic distances
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1966
Sub-type Article (original research)
DOI 10.1071/CH9660993
Volume 19
Issue 6
Start page 993
End page 998
Total pages 6
Subject 1600 Chemistry
Abstract In the theoretical calculations of physical properties of molten salts, the distance of closest approach of the ions, rcj, is a parameter of fundamental importance. For melts where all ions show spherical symmetry rij is a simple parameter. This situation can be assumed for molten nitrates in two cases; either when the nitrate ion is rotating with a period of rotation shorter than the period of oscillation of surrounding cations or when all anion cation orientations are statistically averaged to give an effective spherical rij. Both the assumption of free rotation of the nitrate ion and problems associated with statistical averaging of anion-cation orientations are discussed on the basis of available data.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 26 Jul 2016, 01:59:35 EST by System User