Insertion of group ivb metal dihalides into iron-carbon sigma bonds

Cotton J.D. and Morris G.A. (1978) Insertion of group ivb metal dihalides into iron-carbon sigma bonds. Journal of Organometallic Chemistry, 145 2: 245-254. doi:10.1016/S0022-328X(00)91130-6


Author Cotton J.D.
Morris G.A.
Title Insertion of group ivb metal dihalides into iron-carbon sigma bonds
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1978-01-31
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)91130-6
Volume 145
Issue 2
Start page 245
End page 254
Total pages 10
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract The insertion reaction of GeCl2, SnCl2 and SnBr2 into the iron-carbon sigma bond in the compounds Cp(CO)2FeR (R = methyl, ethyl, n-propyl, p-methoxybenzyl, benzyl and p-trifluoromethyl- benzyl), to yield complexes with the Group IV metal bound to iron, is a radical chain process. A small substituent effect is observed in all cases for the benzyl series, the reaction being favoured by increasing electron donating ability of the para substituent. No clear reactivity trend is noted for the other alkyl complexes.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 12 Jul 2016, 11:03:57 EST by System User