1H NMR and infrared spectra of trimethylplatinum(IV) complexes of β-diketones, thio-β-diketones, and β-iminoketones

Hall J.R. and Swile G.A. (1973) 1H NMR and infrared spectra of trimethylplatinum(IV) complexes of β-diketones, thio-β-diketones, and β-iminoketones. Journal of Organometallic Chemistry, 47 1: 195-215. doi:10.1016/S0022-328X(00)92855-9


Author Hall J.R.
Swile G.A.
Title 1H NMR and infrared spectra of trimethylplatinum(IV) complexes of β-diketones, thio-β-diketones, and β-iminoketones
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1973-01-01
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)92855-9
Volume 47
Issue 1
Start page 195
End page 215
Total pages 21
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract The 1H NMR and infrared spectra of a number of β-diketone, thio-β-diketone, and β-iminoketone derivatives of trimethylplatinum(IV) have been recorded. The spectra indicate that in the parent compounds [Pt(CH3)3L]2, (L = β-iminoketone or thio-β-diketone) the β-iminoketones bridge via the γ-carbon atom as found in β-diketone complexes, while the thio-β-diketones bridge via sulfur atoms. Complexes of the type [Pt(CH3)3LR] (R = a neutral unidentate ligand) and [Pt(CH3)3BipyL] (Bipy = 2,2′-bipyridine) have also been studied.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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