A study of some amine, pyridine and 3,5-lutidine complexes of trimethylplatinum(IV)

Hall J.R. and Swile G.A. (1972) A study of some amine, pyridine and 3,5-lutidine complexes of trimethylplatinum(IV). Journal of Organometallic Chemistry, 42 2: 479-489. doi:10.1016/S0022-328X(00)90099-8


Author Hall J.R.
Swile G.A.
Title A study of some amine, pyridine and 3,5-lutidine complexes of trimethylplatinum(IV)
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1972-09-01
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)90099-8
Volume 42
Issue 2
Start page 479
End page 489
Total pages 11
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract The reactions of trimethylplatinum(IV) compounds with a number of amines have been examined. With ammonia and methylamine, tris-and mono(amine)species have been obtained, but no bis(amine)species apart from [pt(CH3)3(NH3)2I]. With ethylamine the bis(amine)species is formed with excess ligand. The 1H NMR spectra of [Pt(CH3)3LI]2 (L=pyridine, 3,5-lutidine) exhibit evidence for two isomers in solution and an equilibrium of these compounds with [Pt(CH3)3L2I] and [Pt(CH3)3I]4.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 05 Jul 2016, 01:24:33 EST by System User