The stereochemistry of Tutton's salts X2[M(H2O)6](YO4)2

Whitnall J.M. and Kennard C.H.L. (1977) The stereochemistry of Tutton's salts X2[M(H2O)6](YO4)2. Journal of Solid State Chemistry, 22 4: 379-383. doi:10.1016/0022-4596(77)90014-7


Author Whitnall J.M.
Kennard C.H.L.
Title The stereochemistry of Tutton's salts X2[M(H2O)6](YO4)2
Journal name Journal of Solid State Chemistry
ISSN 1095-726X
Publication date 1977-01-01
Sub-type Article (original research)
DOI 10.1016/0022-4596(77)90014-7
Volume 22
Issue 4
Start page 379
End page 383
Total pages 5
Subject 1604 Human Geography
1606 Political Science
2505 Materials Chemistry
Abstract Neutron structure determinations have been made of Tutton's salts, X2[M(H2O)6] (YO4)2, where Y = Se, X = K+, M = Cu2+; Y = S, X = K+, M = Ni2+, Cu2+, Zn2+; X = Rb+, Cs+, M = Cu2+. This work has shown that there are extensive hydrogen networks with almost linear hydrogen bonds from [M(H2O)6]2+ to (YO4)2-. The (H ... O) distance increases in the Cu2+ series for X = K+ to Cs+ but there is no difference for the potassium copper salts when Y = Se or S. Three different distorted [M(H2O)6]2+ octahedra were found in the series (orthorhombic, tetragonal with two long and four short, or four long and two short bonds). The interatomic distances from X+ to the neighboring O in a distorted XO8+ dodecahedron increases with increased cation size, implying that the X+ polyhedron is maintaining its shape.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
Versions
Version Filter Type
Citation counts: Scopus Citation Count Cited 16 times in Scopus Article | Citations
Google Scholar Search Google Scholar
Created: Tue, 28 Jun 2016, 16:26:18 EST by System User