Infra-red, Raman and p.m.r. spectra of trimethyltriammineplatinum(IV) chloride

Clegg D.E. and Hall J.R. (1967) Infra-red, Raman and p.m.r. spectra of trimethyltriammineplatinum(IV) chloride. Spectrochimica Acta Part A: Molecular Spectroscopy, 23 2: 263-272.

Author Clegg D.E.
Hall J.R.
Title Infra-red, Raman and p.m.r. spectra of trimethyltriammineplatinum(IV) chloride
Journal name Spectrochimica Acta Part A: Molecular Spectroscopy   Check publisher's open access policy
ISSN 0584-8539
Publication date 1967
Sub-type Article (original research)
Volume 23
Issue 2
Start page 263
End page 272
Total pages 10
Subject 2200 Engineering
Abstract The infra-red spectra of solid [Pt(CH 3) 3(NH 3) 3]Cl and [Pt(CH 3) 3(ND 3) 3]Cl between 4000 and 300 cm -1 the Raman spectra of the compounds in H 2O and D 2O have been obtained. Vibrational assignments have been made on the basis of C 3v symmetry for the complex ion. In the Raman spectrum of the light compound, lines at 584 and 390 cm -1 were assigned to PtC and PtN stretching vibrations respectively. In the N-deuterated compound the corresponding frequencies were 585 and 364 cm -1. The infra-red spectra of the solid compounds included bands at 581, 410 and 377 cm -1 (light) and 585, 381 and 352 cm -1 (N-deuterated) which were attributed to skeletal stretching vibrations. From the p.m.r. spectrum J 195PtCH3 was found to be 71 c/s. The Raman spectra and solution behaviour of Pt[(CH 3) 3(NH 3) 3] + and [Pt(NH 3) 6] 4+ were compared.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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