Structure of molten nitrates. III. Vibrational spectra of LiNO3, NaNO3, and AgNO3

James, David W. and Leong, W. H. (1969) Structure of molten nitrates. III. Vibrational spectra of LiNO3, NaNO3, and AgNO3. Journal of Chemical Physics, 51 2: 640-646.

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Author James, David W.
Leong, W. H.
Title Structure of molten nitrates. III. Vibrational spectra of LiNO3, NaNO3, and AgNO3
Formatted title
Structure of molten nitrates. III. Vibrational spectra of LiNO3, NaNO3, and AgNO3
Journal name Journal of Chemical Physics   Check publisher's open access policy
ISSN 0021-9606
1089-7690
Publication date 1969-07-15
Sub-type Article (original research)
Open Access Status File (Publisher version)
Volume 51
Issue 2
Start page 640
End page 646
Total pages 7
Place of publication Melville, NY, United States
Publisher A I P Publishing LLC
Language eng
Abstract The Raman spectra of the molten nitrates of lithium,sodium, and silver change as the temperature is raised. Close to the melting point well‐developed low‐frequency modes can be distinguished close to the exciting line while at higher temperature these have become somewhat broader but still quite distinct. There are also changes in the magnitude of the splitting of degenerate modes and in the energy of the other vibrations. The spectra have been interpreted on the basis of a quasicrystalline model in which cubic packing is assumed. Spectral changes from the solid, volume change on fusion, entropy changes, and molten‐state radial distribution functions are explained on the basis of the model.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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