Sulfur dioxide insertion into carbontin bonds. II. Rearrangements accompanying insertion

Fong C.W. and Kitching W. (1970) Sulfur dioxide insertion into carbontin bonds. II. Rearrangements accompanying insertion. Journal of Organometallic Chemistry, 22 1: 95-106. doi:10.1016/S0022-328X(00)83081-8


Author Fong C.W.
Kitching W.
Title Sulfur dioxide insertion into carbontin bonds. II. Rearrangements accompanying insertion
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1970
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)83081-8
Volume 22
Issue 1
Start page 95
End page 106
Total pages 12
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract A number of allylic, allenylic and 2-propynylic (R′) derivatives of tin of the type R3SnR′ have been synthesized, and shown to undergo ready insertion of sulfur dioxide into the SnR′ bond. Rearrangement accompanies insertion so that the products have the alternate allylic, 2-propynylic and allenylic structures respectively. Di-insertion occurs only when groups attached to tin are quite susceptible to electrophilic cleavage. NMR data for the compounds are reported.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 28 Jun 2016, 02:46:02 EST by System User