Regiochemistry of some electrophilic cleavages of penta-2,4-dienyl-silanes, -germanes and -stannanes

Jones M. and Kitching W. (1983) Regiochemistry of some electrophilic cleavages of penta-2,4-dienyl-silanes, -germanes and -stannanes. Journal of Organometallic Chemistry, 247 1: . doi:10.1016/S0022-328X(00)98839-9


Author Jones M.
Kitching W.
Title Regiochemistry of some electrophilic cleavages of penta-2,4-dienyl-silanes, -germanes and -stannanes
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1983-05-03
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)98839-9
Volume 247
Issue 1
Total pages 1
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract (2,4-Pentadienyl)- and (2,4-hexadienyl)-trimethyl-silanes, -germanes and -stannanes experience trifluoroacetolysis regioselectively at the ε{lunate}-position, whereas sulfur dioxide reacts regiospecifically at the γ-position of the stannanes. The kinetic γ-sulfinate efficiently rearranges to the (conjugated) dienylmethylsulfinates.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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