Carbon-13-nuclear magnetic resonance spectra of 5-coordinate tris-olefin complexes of rhodium(I)

Clark P.W. and Jones A.J. (1976) Carbon-13-nuclear magnetic resonance spectra of 5-coordinate tris-olefin complexes of rhodium(I). Journal of Organometallic Chemistry, 122 3: . doi:10.1016/S0022-328X(00)82405-5


Author Clark P.W.
Jones A.J.
Title Carbon-13-nuclear magnetic resonance spectra of 5-coordinate tris-olefin complexes of rhodium(I)
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1976-12-21
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)82405-5
Volume 122
Issue 3
Total pages 1
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Studies of the 13C N.M.R. spectra of the series RhX[P(Ch2CH2CHCH2)3] and RhX[P(CH2CH2CH2CHCH2) 3] where x Cl or Br have revealed that (a) the J(103Rh-13C) (olefin) for the complexes studied is only 1 2 - 1 3 that found for square-planar complexes, and (b) the fluxional character in the olefinic carbons observed for the compounds RhX[P(CH2CH2CHCH2)3] is related to the partial rotation of the olefin about the rhodium-olefin bond.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 14 Jun 2016, 05:41:44 EST by System User