Silylcuprate routes to cyclohex-2-enylsilanes

Laycock B., Maynard I., Wickham G. and Kitching W. (1988) Silylcuprate routes to cyclohex-2-enylsilanes. Australian Journal of Chemistry, 41 5: 693-700. doi:10.1071/CH9880693


Author Laycock B.
Maynard I.
Wickham G.
Kitching W.
Title Silylcuprate routes to cyclohex-2-enylsilanes
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1988
Sub-type Article (original research)
DOI 10.1071/CH9880693
Volume 41
Issue 5
Start page 693
End page 700
Total pages 8
Subject 1600 Chemistry
Abstract The efficacy of the dimethyl(phenyl)silylcuprate and (to a lesser extent) the methyl-diphenylsilylcuprate reagents in converting cyclohex-2-enyl chlorides into the corresponding allylsilanes has been investigated. The presence of copper(I) greatly suppresses formation of the coupled hydrocarbon, and promotes stereo- and regio-selective carbon-silicon bond formation, in a predominantly anti-SN2’ manner. Spectroscopic characterization of the diastereomeric silanes is presented. Grignard routes to some of these silanes are described.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Tue, 14 Jun 2016, 01:51:27 EST by System User