Catalysts containing the adamantane scaffold

Kylie A. Agnew-Francis and Williams, Craig M. (2016) Catalysts containing the adamantane scaffold. Advanced Synthesis and Catalysis, 358 5: 675-700. doi:10.1002/adsc.201500949


Author Kylie A. Agnew-Francis
Williams, Craig M.
Title Catalysts containing the adamantane scaffold
Journal name Advanced Synthesis and Catalysis   Check publisher's open access policy
ISSN 1615-4169
1615-4150
Publication date 2016-02-18
Sub-type Article (original research)
DOI 10.1002/adsc.201500949
Open Access Status Not Open Access
Volume 358
Issue 5
Start page 675
End page 700
Total pages 27
Place of publication Weinheim, Germany
Publisher Wiley - V C H Verlag
Collection year 2017
Language eng
Abstract The bulky, but symmetrically beautiful, adamantane ring system is now pervasive throughout physical, medicinal and synthetic chemistry, since it was first discovered in 1924 and coined “dekaterpene”. This fascinating name lived up to its natural product roots when adamantane was isolated from crude oil in 1933, but it was not until 1957 in a landmark contribution by Paul von Ragué Schleyer that adamantane was made readily accessible through synthesis. Beyond the legacy to physical and medicinal chemistry, the adamantane moiety has been quintessential in the development of some of the most important catalysts to date. Considering adamantane’s impact on catalyst development past, present and future, this subject is for the first time reviewed herein.
Keyword Adamantane
Adamantyl group
Ligand design
Metal catalysis
Organocatalysis
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: HERDC Pre-Audit
School of Chemistry and Molecular Biosciences
 
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Created: Fri, 19 Feb 2016, 10:05:08 EST by Mrs Louise Nimwegen on behalf of School of Chemistry & Molecular Biosciences