Calibrating the coordination chemistry tool chest: metrics of bi- and tridentate ligands

Aguila, David, Escribano, Esther, Speed, Saskia, Talancon, Daniel, Yerman, Luis and Alvarez, Santiago (2009) Calibrating the coordination chemistry tool chest: metrics of bi- and tridentate ligands. Dalton Transactions, 33: 6610-6625. doi:10.1039/b904938j


Author Aguila, David
Escribano, Esther
Speed, Saskia
Talancon, Daniel
Yerman, Luis
Alvarez, Santiago
Title Calibrating the coordination chemistry tool chest: metrics of bi- and tridentate ligands
Journal name Dalton Transactions   Check publisher's open access policy
ISSN 1477-9226
1477-9234
Publication date 2009
Sub-type Article (original research)
DOI 10.1039/b904938j
Open Access Status Not Open Access
Issue 33
Start page 6610
End page 6625
Total pages 16
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Language eng
Subject 1604 Human Geography
Abstract Bi- and multidentate ligands form part of the tools commonly used for designing coordination and supramolecular complexes with desired stereochemistries. Parameters and concepts usually employed include the normalized bite of bidentate ligands, their cis- or trans-coordinating ability, their rigidity or flexibility, or the duality of some ligands that can act in chelating or dinucleating modes. In this contribution we present a structural database study of over one hundred bi- and tridentate ligands that allows us to parametrize their coordinating properties and discuss the relevance of such parameters for the choice of coordination polyhedron or coordination sites.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Civil Engineering Publications
 
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