A large spin-crossover [Fe4L4]8+ tetrahedral cage

Li, Li, Saigo, Naoto, Zhang, Yingjie, Fanna, Daniel J., Shepherd, Nicholas D., Clegg, Jack K., Zheng, Rongkun, Hayami, Shinya, Lindoy, Leonard F., Aldrich-Wright, Janice R., Li, Chun-Guang, Reynolds, Jason K., Harman, David G. and Li, Feng (2015) A large spin-crossover [Fe4L4]8+ tetrahedral cage. Journal of Materials Chemistry C, 3 30: 7878-7882. doi:10.1039/c5tc00991j

Author Li, Li
Saigo, Naoto
Zhang, Yingjie
Fanna, Daniel J.
Shepherd, Nicholas D.
Clegg, Jack K.
Zheng, Rongkun
Hayami, Shinya
Lindoy, Leonard F.
Aldrich-Wright, Janice R.
Li, Chun-Guang
Reynolds, Jason K.
Harman, David G.
Li, Feng
Title A large spin-crossover [Fe4L4]8+ tetrahedral cage
Formatted title
A large spin-crossover [Fe4L4]8+ tetrahedral cage
Journal name Journal of Materials Chemistry C   Check publisher's open access policy
ISSN 2050-7526
Publication date 2015-08-14
Sub-type Article (original research)
DOI 10.1039/c5tc00991j
Open Access Status Not Open Access
Volume 3
Issue 30
Start page 7878
End page 7882
Total pages 5
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Collection year 2016
Language eng
Formatted abstract
A large discrete face-capped tetranuclear iron(II) cage, [Fe4L4](BF4)8·n(solvent), was synthesised via metal-ion directed self-assembly. The cage is formed from a rigid tritopic ligand that incorporates chelating imidazole-imine functional groups. The cage displays temperature induced spin-crossover and LIESST effects and is amongst the largest iron(II) tetrahedral cages with such properties reported. The synthesis, structure and magnetic properties of this new metallo-cage are presented.
Keyword Tetranuclear iron cage
LIESST effects
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2016 Collection
School of Chemistry and Molecular Biosciences
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