Ketenes from N-(2-Pyridyl)amides

Plug, Carsten, Kanaani, Hussein and Wentrup, Curt (2015) Ketenes from N-(2-Pyridyl)amides. Australian Journal of Chemistry, 68 4: 687-692. doi:10.1071/CH14714


Author Plug, Carsten
Kanaani, Hussein
Wentrup, Curt
Title Ketenes from N-(2-Pyridyl)amides
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 0004-9425
1445-0038
Publication date 2015
Sub-type Article (original research)
DOI 10.1071/CH14714
Open Access Status
Volume 68
Issue 4
Start page 687
End page 692
Total pages 6
Place of publication Clayton, VIC, Australia
Publisher C S I R O Publishing
Collection year 2016
Language eng
Formatted abstract
Methoxycarbonylketene 4a, methoxycarbonyl(methyl)ketene 4b, chloroketene 4c, cyanoketene 4d, diphenylketene 4e, and 2-pyridylketene 4f have been generated by flash vacuum thermolysis of the corresponding 2-pyridylacetamide derivatives 3a-f and isolated in Ar matrices for FT-IR spectroscopic characterisation. The N-(2-pyridyl)-2-pyridylacetamide 3f yielded 2-pyridyl isocyanate in addition to 2-pyridylketene.
Keyword Flash vacuum thermolysis
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2016 Collection
School of Chemistry and Molecular Biosciences
 
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Created: Fri, 08 May 2015, 13:41:37 EST by Mrs Louise Nimwegen on behalf of School of Chemistry & Molecular Biosciences