Hybrid Reverse Monte Carlo simulation of amorphous carbon: distinguishing between competing structures obtained using different modeling protocols

Farmahini, Amir H. and Bhatia, Suresh K. (2015) Hybrid Reverse Monte Carlo simulation of amorphous carbon: distinguishing between competing structures obtained using different modeling protocols. Carbon, 83 53-70. doi:10.1016/j.carbon.2014.11.013

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Author Farmahini, Amir H.
Bhatia, Suresh K.
Title Hybrid Reverse Monte Carlo simulation of amorphous carbon: distinguishing between competing structures obtained using different modeling protocols
Journal name Carbon   Check publisher's open access policy
ISSN 0008-6223
1873-3891
Publication date 2015-03-01
Year available 2014
Sub-type Article (original research)
DOI 10.1016/j.carbon.2014.11.013
Volume 83
Start page 53
End page 70
Total pages 18
Place of publication Kidlington, Oxford United Kingdom
Publisher Pergamon Press
Collection year 2015
Language eng
Formatted abstract
We explore different multi-stage and multi-constraint modeling strategies using the Hybrid Reverse Monte Carlo (HRMC) technique to develop realistic models for the amorphous structure of silicon carbide derived-carbon, and investigate the effect of modeling parameters on the development of nano-structural features of the constructed models. It is shown that application of long simulations with slow thermal quench rate is essential for modeling of amorphous structures. Nevertheless, very slow quenching rates are shown to lead to the formation of configurations with large fraction of sp2 carbon, lacking the level of disorder required to match structure-related experimental data. The predicted gas adsorption isotherms are very sensitive to the pore size distribution (PSD), thus the final structure must reasonably reproduce the total pore volume and pore size distribution of the experimental sample. The frequently-observed strong first peak of the DFT-based PSD obtained from argon adsorption is shown to be an artifact of argon inaccessibility. Pore accessibility analysis of the constructed models, as well as MD simulations of gas transport demonstrate that the HRMC constructed structures contain short-range structural anisotropy, however the models are successful in capturing the long range internal energy barriers of amorphous carbon for methane.
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Published online ahead of print 13 Nov 2014

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Chemical Engineering Publications
Official 2015 Collection
 
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