Bifunctional copper(II) chelators from the coupling of the encapsulating ligand 1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane (AMN3S3sar) with carboxylic acids; applications of the coupling agent DMT-MM

Lee, Hui Hui, Lim, Peiying Alinia, Vu, Hoan, Poulsen, Sally-Ann and Gahan, Lawrence R. (2015) Bifunctional copper(II) chelators from the coupling of the encapsulating ligand 1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane (AMN3S3sar) with carboxylic acids; applications of the coupling agent DMT-MM. Polyhedron, 85 627-634. doi:10.1016/j.poly.2014.09.025


Author Lee, Hui Hui
Lim, Peiying Alinia
Vu, Hoan
Poulsen, Sally-Ann
Gahan, Lawrence R.
Title Bifunctional copper(II) chelators from the coupling of the encapsulating ligand 1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane (AMN3S3sar) with carboxylic acids; applications of the coupling agent DMT-MM
Formatted title
Bifunctional copper(II) chelators from the coupling of the encapsulating ligand 1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane (AMN3S3sar) with carboxylic acids; applications of the coupling agent DMT-MM
Journal name Polyhedron   Check publisher's open access policy
ISSN 0277-5387
1873-3719
Publication date 2015-01-08
Year available 2014
Sub-type Article (original research)
DOI 10.1016/j.poly.2014.09.025
Open Access Status
Volume 85
Start page 627
End page 634
Total pages 8
Place of publication Kidlington, Oxford United Kingdom
Publisher Pergamon Press
Collection year 2014
Language eng
Formatted abstract
Reaction of 1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]icosane (AMN3S3sar) with the amide coupling agent 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride (DMT-MM) and 4-nitrobenzoic acid, the protected amine 4-(1,3-dioxoisoindolin-2-yl)benzoic acid and the tricarboxylic acid, benzene-1,3,5-tricarboxylic acid (trimesic acid) resulted in the three new ligands N3S3amideSarArNO2, N3S3amideSarAr, and (AMN3S3sar)3TMA. Two of the respective copper(II) complexes have been isolated and characterized.
Keyword Encapsulated
Complex
Coupling reagent
Copper
Mass spectrometry
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Published online ahead of print 22 Oct 2014

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2015 Collection
School of Chemistry and Molecular Biosciences
 
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