Stable GaX2, InX2 and TlX2 radicals

Protchenko, Andrey V., Dange, Deepak, Harmer, Jeffrey R., Tang, Christina Y., Schwarz, Andrew D., Kelly, Michael J., Phillips, Nicholas, Tirfoin, Remi, Birjkumar, Krishna Hassomal, Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip and Aldridge, Simon (2014) Stable GaX2, InX2 and TlX2 radicals. Nature Chemistry, 6 4: 315-319. doi:10.1038/nchem.1870

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Author Protchenko, Andrey V.
Dange, Deepak
Harmer, Jeffrey R.
Tang, Christina Y.
Schwarz, Andrew D.
Kelly, Michael J.
Phillips, Nicholas
Tirfoin, Remi
Birjkumar, Krishna Hassomal
Jones, Cameron
Kaltsoyannis, Nikolas
Mountford, Philip
Aldridge, Simon
Title Stable GaX2, InX2 and TlX2 radicals
Formatted title
Stable GaX2, InX2 and TlX2 radicals
Journal name Nature Chemistry   Check publisher's open access policy
ISSN 1755-4330
1755-4349
Publication date 2014-04
Year available 2014
Sub-type Article (original research)
DOI 10.1038/nchem.1870
Open Access Status
Volume 6
Issue 4
Start page 315
End page 319
Total pages 5
Place of publication London, United Kingdom
Publisher Nature Publishing Group
Collection year 2015
Language eng
Formatted abstract
The chemistry of the Group 13 metals is dominated by the +1 and +3 oxidation states, and simple monomeric M(ɪɪ) species are typically short-lived, highly reactive species. Here we report the first thermally robust monomeric MX2 radicals of gallium, indium and thallium. By making use of sterically demanding boryl substituents, compounds of the type M(ɪɪ)(boryl)2 (M = Ga, In, Tl) can be synthesized. These decompose above 130 °C and are amenable to structural characterization in the solid state by X-ray crystallography. Electron paramagnetic resonance and computational studies reveal a dominant metal-centred character for all three radicals (>70% spin density at the metal). M(ɪɪ) species have been invoked as key short-lived intermediates in well-known electron-transfer processes; consistently, the chemical behaviour of these novel isolated species reveals facile one-electron shuttling processes at the metal centre.
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2015 Collection
Centre for Advanced Imaging Publications
 
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Citation counts: TR Web of Science Citation Count  Cited 24 times in Thomson Reuters Web of Science Article | Citations
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Created: Tue, 18 Feb 2014, 18:13:19 EST by Sandrine Ducrot on behalf of Centre for Advanced Imaging