Bidirectional regulation of halide binding in a heterometallic supramolecular cube

Ramsay, William J., Ronson, Tanya K., Clegg, Jack K. and Nitschke, Jonathan R. (2013) Bidirectional regulation of halide binding in a heterometallic supramolecular cube. Angewandte Chemie International Edition, 52 50: 13439-13443. doi:10.1002/anie.201307478

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Author Ramsay, William J.
Ronson, Tanya K.
Clegg, Jack K.
Nitschke, Jonathan R.
Title Bidirectional regulation of halide binding in a heterometallic supramolecular cube
Journal name Angewandte Chemie International Edition   Check publisher's open access policy
ISSN 1433-7851
1521-3773
Publication date 2013
Year available 2013
Sub-type Article (original research)
DOI 10.1002/anie.201307478
Open Access Status
Volume 52
Issue 50
Start page 13439
End page 13443
Total pages 5
Place of publication Weinheim, Germany
Publisher Wiley - V C H Verlag
Collection year 2014
Language eng
Formatted abstract
Complex cubes: In a cationic supramolecular cube, coordinatively unsaturated metal centers in the walls of the host provided binding sites for neutral or negatively charged guests. The binding of an initial guest (CF3CO2, OPMe3, NH3, or NMe3) either cooperatively enhanced or competitively inhibited the binding of a second guest (halide ion).
Keyword Anion binding
Association constants
Host–guest systems
Metal–organic capsules
Supramolecular chemistry
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Article first published online: 14 NOV 2013

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2014 Collection
School of Chemistry and Molecular Biosciences
 
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Citation counts: TR Web of Science Citation Count  Cited 24 times in Thomson Reuters Web of Science Article | Citations
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Created: Fri, 15 Nov 2013, 13:32:27 EST by Mrs Louise Nimwegen on behalf of School of Chemistry & Molecular Biosciences