3-Hydroxypyridin-2-one complexes of near-infrared (NIR) emitting lanthanides: Sensitization of holmium(III) and praseodymium(III) in aqueous solution

Moore, Evan G., Szigethy, Geza, Xu, Jide, Palsson, Lars-Olof, Beeby, Andrew and Raymond, Kenneth N. (2008) 3-Hydroxypyridin-2-one complexes of near-infrared (NIR) emitting lanthanides: Sensitization of holmium(III) and praseodymium(III) in aqueous solution. Angewandte Chemie (International Edition), 47 49: 9500-9503. doi:10.1002/anie.200802337


Author Moore, Evan G.
Szigethy, Geza
Xu, Jide
Palsson, Lars-Olof
Beeby, Andrew
Raymond, Kenneth N.
Title 3-Hydroxypyridin-2-one complexes of near-infrared (NIR) emitting lanthanides: Sensitization of holmium(III) and praseodymium(III) in aqueous solution
Journal name Angewandte Chemie (International Edition)   Check publisher's open access policy
ISSN 1433-7851
1521-3773
Publication date 2008-11-24
Year available 2008
Sub-type Article (original research)
DOI 10.1002/anie.200802337
Volume 47
Issue 49
Start page 9500
End page 9503
Total pages 4
Place of publication Weinheim, Germany
Publisher V C H Verlag
Language eng
Formatted abstract
Ho ho ho! Characteristic visible and near-infrared (NIR) emission bands of the PrIII and HoIII complexes of the tetradentate 1-methyl-3-hydroxypyridin-2-one chromophore are observed in aqueous solution. The HoIII complex has been structurally characterized and, for the first time for a HoIII complex, the kinetics of the luminescence decay in the NIR region have been determined in solution.
Keyword Near-infrared
Holmium
Lanthanides;
Luminescence
Praseodymium
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes Published online 29 October 2008

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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Created: Mon, 09 Sep 2013, 10:11:59 EST by Evan Moore on behalf of School of Chemistry & Molecular Biosciences