Optimization of a direct carbon fuel cell for operation below 700 degrees C

Xu, Xiaoyong, Zhou, Wei, Liang, Fengli and Zhu, Zhonghua (2013) Optimization of a direct carbon fuel cell for operation below 700 degrees C. International Journal of Hydrogen Energy, 38 13: 5367-5374. doi:10.1016/j.ijhydene.2013.02.066


Author Xu, Xiaoyong
Zhou, Wei
Liang, Fengli
Zhu, Zhonghua
Title Optimization of a direct carbon fuel cell for operation below 700 degrees C
Journal name International Journal of Hydrogen Energy   Check publisher's open access policy
ISSN 0360-3199
1879-3487
Publication date 2013-05
Year available 2013
Sub-type Article (original research)
DOI 10.1016/j.ijhydene.2013.02.066
Volume 38
Issue 13
Start page 5367
End page 5374
Total pages 8
Place of publication Camden, London, United Kingdom
Publisher Elsevier Ltd
Collection year 2014
Language eng
Formatted abstract
Direct carbon fuel cells (DCFCs) are the most efficient technology to convert solid carbon energy to electricity and thus could have a major impact on reducing fuel consumption and CO2 emissions. The development of DCFCs to commercialisation stage is largely prohibited by their poor power densities due to the high resistive loss from anode. Here, we report a high-performance Sm0.2Ce0.8O1.9 electrolyte-supported hybrid DCFC with Ba0.5Sr0.5Co 0.8Fe0.2O3-δ cathode and optimised anode configuration. The catalytic oxidation of carbon is improved, which results in an area specific resistance of only 0.41 cm2 at 650 °C at the anode. The hybrid DCFC achieves a peak power density of 113.1 mW cm-2 at 650 °C operating on activated carbon. The stability of the fuel cell has also been improved due to the optimised current collection.
Keyword Direct carbon fuel cell
Electrolyte-supported fuel cell
Solid carbon
Carbonates
Solid Oxide
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Chemical Engineering Publications
Official 2014 Collection
 
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Citation counts: TR Web of Science Citation Count  Cited 12 times in Thomson Reuters Web of Science Article | Citations
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Created: Sun, 30 Jun 2013, 00:25:12 EST by System User on behalf of School of Chemical Engineering