Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor: spectral and temperature dependent magneto structural correlation

Datta, Amitabha, Clegg, Jack K., Huang, Jui-Hsien, Pevec, Andrej, Garribba, Eugenio and Fondo, Matilde (2012) Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor: spectral and temperature dependent magneto structural correlation. Inorganic Chemistry Communications, 24 216-220. doi:10.1016/j.inoche.2012.07.017


Author Datta, Amitabha
Clegg, Jack K.
Huang, Jui-Hsien
Pevec, Andrej
Garribba, Eugenio
Fondo, Matilde
Title Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor: spectral and temperature dependent magneto structural correlation
Journal name Inorganic Chemistry Communications   Check publisher's open access policy
ISSN 1387-7003
1879-0259
Publication date 2012-10
Sub-type Article (original research)
DOI 10.1016/j.inoche.2012.07.017
Volume 24
Start page 216
End page 220
Total pages 5
Place of publication Amsterdam, Netherlands
Publisher Elsevier
Collection year 2013
Language eng
Formatted abstract
A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.
Keyword Copper(II)
Salicyladimine
Hydroxo bridge
Spectroscopic study
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Available online: 13 July 2012.

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2013 Collection
School of Chemistry and Molecular Biosciences
 
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