Hexagonally ordered mesoporous highly acidic AlSBA-15 with different morphology: an efficient catalyst for acetylation of aromatics

Vinu, Ajayan, Justus, Josena, Anand, C., Sawant, Dhanashri P., Ariga, Katsuhiko, Mori, Toshiyuki, Srinivasu, Pavuluri, Balasubramanian, Veerappan V., Velmathi, Sivan and Alam, Sher (2008) Hexagonally ordered mesoporous highly acidic AlSBA-15 with different morphology: an efficient catalyst for acetylation of aromatics. Microporous and Mesoporous Materials, 116 1-3: 108-115. doi:10.1016/j.micromeso.2008.03.033


Author Vinu, Ajayan
Justus, Josena
Anand, C.
Sawant, Dhanashri P.
Ariga, Katsuhiko
Mori, Toshiyuki
Srinivasu, Pavuluri
Balasubramanian, Veerappan V.
Velmathi, Sivan
Alam, Sher
Title Hexagonally ordered mesoporous highly acidic AlSBA-15 with different morphology: an efficient catalyst for acetylation of aromatics
Journal name Microporous and Mesoporous Materials   Check publisher's open access policy
ISSN 1387-1811
1873-3093
Publication date 2008-12
Sub-type Article (original research)
DOI 10.1016/j.micromeso.2008.03.033
Volume 116
Issue 1-3
Start page 108
End page 115
Total pages 8
Place of publication Amsterdam, Netherlands
Publisher Elsevier
Language eng
Formatted abstract
Hexagonally ordered mesoporous AlSBA-15 with different nSi/nAl ratios and morphology have been hydrothermally synthesized using the non-ionic copolymer Pluronic P123 surfactant as the structure directing agent and characterized by XRD, N2 adsorption-desorption, SEM-EDX, elemental mapping, 27Al MAS NMR, and NH3-TPD. It has been found that the shape and size of the particles can be controlled by the simple adjustment of the amount of Al content in the silica framework. Polygonal shaped particles with small (ca. 600 nm) and uniform size are observed for the AlSBA-15 materials with higher amount of Al in the framework. Acetylation of the aromatic compounds veratrole, anisole, and 2-methoxynaphthalene with acetic anhydride has been investigated over AlSBA-15 with different nSi/nAl ratios under liquid phase conditions and the results are discussed. The activity of the AlSBA-15 catalysts in the acetylation of veratrole was found to increase with decreasing the nSi/nAl ratio up to 45, and decreased with the further loading of Al in the framework. The effect of various reaction parameters such as reactant mole ratio, temperature, and catalyst concentration on the acetic anhydride conversion has been investigated in detail. The activity of the AlSBA-15 catalysts with different Al contents in the acetylation of veratrole was compared with various zeolite catalysts such as BEA, FAU, MOR, MFI, and AlMCM-41(22) where the number in parentheses denotes the nSi/nAl ratio. It has been found that AlSBA-15 with the nSi/nAl ratio of 45 showed the best performance in the acetylation of veratrole, with high acetic anhydride conversion and 100% selectivity to 3,4-dimethoxyacetophenone under the optimized reaction conditions. Moreover, the kinetics of the acetylation of veratrole over AlSBA-15 catalysts is discussed in detail.
Keyword Adsorption
Mesoporous
Acetylation
Veratrole
Acetic anhydride
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: Australian Institute for Bioengineering and Nanotechnology Publications
 
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