Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units

Zhu, Bi-Xue, Zhang, Qi-Long, Zhang, Yun-Qian, Tao, Zhu, Clegg, Jack K., Reimers, Jeffrey R., Lindoy, Leonard F. and Wei, Gang (2009) Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units. Dalton Transactions, 25: 4896-4900. doi:10.1039/b903467f

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Author Zhu, Bi-Xue
Zhang, Qi-Long
Zhang, Yun-Qian
Tao, Zhu
Clegg, Jack K.
Reimers, Jeffrey R.
Lindoy, Leonard F.
Wei, Gang
Title Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units
Journal name Dalton Transactions   Check publisher's open access policy
ISSN 1477-9226
1477-9234
Publication date 2009-01
Sub-type Article (original research)
DOI 10.1039/b903467f
Open Access Status File (Publisher version)
Issue 25
Start page 4896
End page 4900
Total pages 5
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Language eng
Formatted abstract
Diastereopure (1R,2R)-N,N′-bis(acetylacetone)cyclohexanedi-imine L 1 and its corresponding (1R,2R)L 1/(1S,2S)L 2 enantiomeric mixture react with AgNO 3 to yield the unusual coordination polymer [Ag 2(L 1)(L 2)(NO 3) 2] n (1) and the unique trimetallic discrete species {[Ag 3(L 1) 33-O,O,O- NO 3)(H 2O) 3] 2(NO 3)} (NO 3) 3·8.5H 2O (2) which incorporates a symmetrical μ 3-bridging nitrato group that gives rise to a C 3-symmetric triskelion motif; both species also feature γ-carbon η 1 aryl-like coordination of neutral bridging acetylacetone-imine units to the respective Ag(I) centres.
Keyword Effective core potentials
Molecular calculations
Coordination polymers
Supramolecular isomerism
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes First published on the web 08 May 2009.

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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