Bis(2,2 ',2 ''-nitrilotriethanol)cobalt(II) bis(acetate)

Ward, Antony J., Burger, Matija, Aquino, Cindy, Clegg, Jack K., Turner, Peter, Masters, Anthony F. and Maschmeyer, Thomas (2006) Bis(2,2 ',2 ''-nitrilotriethanol)cobalt(II) bis(acetate). Acta Crystallographica Section E-Structure Reports Online, 62 10: M2429-M2431. doi:10.1107/S160053680603443X


Author Ward, Antony J.
Burger, Matija
Aquino, Cindy
Clegg, Jack K.
Turner, Peter
Masters, Anthony F.
Maschmeyer, Thomas
Title Bis(2,2 ',2 ''-nitrilotriethanol)cobalt(II) bis(acetate)
Formatted title
Bis(2,2′,2″-nitrilotriethanol)cobalt(II) bis(acetate)
Journal name Acta Crystallographica Section E-Structure Reports Online   Check publisher's open access policy
ISSN 1600-5368
Publication date 2006-10
Sub-type Article (original research)
DOI 10.1107/S160053680603443X
Open Access Status DOI
Volume 62
Issue 10
Start page M2429
End page M2431
Total pages 3
Place of publication Malden, MA United States
Publisher Wiley-Blackwell Publishing
Collection year 2006
Language eng
Formatted abstract
The title compound, [Co(C6H15NO3)2](CH3CO2)2, contains two triethanolamine ligands bound to a Co2+ metal centre, which lies on a crystallographic inversion site such that the asymmetric unit contains half of the cation and one acetate anion. The triethanolamine ligands coordinate via each axial N and two of the three O atoms, while the third arm of the ligand is pendant with the hydroxyl group pointing away from the metal centre. The acetate anions are hydrogen bonded to the coordinated hydroxyl groups and also to the free arm, forming a two-dimensional sheet-like motif.
Keyword Cyclohexane Oxidation
Decomposition
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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