A mixed-spin molecular square with a hybrid [2 x 2]grid/metallocyclic architecture

Li, Feng, Clegg, Jack K., Goux-Capes, Laurence, Chastanet, Guillaume, D'Alessandro, Deanna M., Letard, Jean-Francois and Kepert, Cameron J. (2011) A mixed-spin molecular square with a hybrid [2 x 2]grid/metallocyclic architecture. Angewandte Chemie-International Edition, 50 12: 2820-2823. doi:10.1002/anie.201007409


Author Li, Feng
Clegg, Jack K.
Goux-Capes, Laurence
Chastanet, Guillaume
D'Alessandro, Deanna M.
Letard, Jean-Francois
Kepert, Cameron J.
Title A mixed-spin molecular square with a hybrid [2 x 2]grid/metallocyclic architecture
Journal name Angewandte Chemie-International Edition   Check publisher's open access policy
ISSN 1433-7851
1521-3773
Publication date 2011-01
Sub-type Article (original research)
DOI 10.1002/anie.201007409
Volume 50
Issue 12
Start page 2820
End page 2823
Total pages 4
Place of publication Weinheim, Germany
Publisher Wiley - V C H Verlag GmbH
Language eng
Formatted abstract
Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-Fe II complex that features low-spin (LS) and high-spin (HS) Fe II centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2× 2]grid/metallocyclic architecture (see picture).
Keyword Cyanide ligand
Iron
Magnetic properties
Metallomacrocycles
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes Article first published online: 24 February 2011.

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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