A new nickel(II) coordination polymer derived from [Ni(N,N-ethylenebis(1,1,1-trifluoroacetylacetoneiminato)] and 1,4-diazabicyclo[2.2.2]octane

Meng, Qinghua, Clegg, Jack K., Jolliffe, Katrina A., Lindoy, Leonard F., Lan, Minbo and Wei, Gang (2010) A new nickel(II) coordination polymer derived from [Ni(N,N-ethylenebis(1,1,1-trifluoroacetylacetoneiminato)] and 1,4-diazabicyclo[2.2.2]octane. Inorganic Chemistry Communications, 13 4: 558-562. doi:10.1016/j.inoche.2010.02.004

Author Meng, Qinghua
Clegg, Jack K.
Jolliffe, Katrina A.
Lindoy, Leonard F.
Lan, Minbo
Wei, Gang
Title A new nickel(II) coordination polymer derived from [Ni(N,N-ethylenebis(1,1,1-trifluoroacetylacetoneiminato)] and 1,4-diazabicyclo[2.2.2]octane
Journal name Inorganic Chemistry Communications   Check publisher's open access policy
ISSN 1387-7003
Publication date 2010-04
Sub-type Article (original research)
DOI 10.1016/j.inoche.2010.02.004
Volume 13
Issue 4
Start page 558
End page 562
Total pages 5
Place of publication Amsterdam, Netherlands
Publisher Elsevier
Language eng
Formatted abstract
The presence of two electron-withdrawing CF 3 groups in [Ni{N,N-ethylenebis(1,1,1-trifluoroacetylacetoneiminato)}] (NiL) has been demonstrated to promote axial coordination by pyridine (Py) ligands to form the corresponding octahedral base adduct complex in the solid state, while the corresponding solid products do not form in the absence of the CF 3 groups. The change to octahedral geometry is accompanied by a spin-state change of the nickel from low- to high-spin. The structure of the octahedral product, [NiL(Py) 2], has been confirmed by X-ray diffraction. In an extension of this study, [NiL] was reacted with the difunctional (stronger) base 1,4-diazabicyclo[2.2.2]octane (dabco); the X-ray structure of the product confirmed the formation of a one-dimensional coordination polymer in which dabco axially bridges [NiL] units in a highly linear fashion. This product represents an example of a new class of one-dimensional polymeric structures in which a difunctional base (in this case dabco) links square planar [NiL] units of the present type.
Keyword Coordination polymer
Schiff base
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes Available online 11 February 2010.

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
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