Predesigned hexanuclear Cu II and Cu II/Ni II metallacycles featuring six-node metallacoronand structural motifs

Li, Feng, Clegg, Jack K., Jensen, Paul, Fisher, Keith, Lindoy, Leonard F., Meehan, George V., Moubaraki, Boujemaa and Murray, Keith S. (2009) Predesigned hexanuclear Cu II and Cu II/Ni II metallacycles featuring six-node metallacoronand structural motifs. Angewandte Chemie-International Edition, 48 38: 7059-7063. doi:10.1002/anie.200903185


Author Li, Feng
Clegg, Jack K.
Jensen, Paul
Fisher, Keith
Lindoy, Leonard F.
Meehan, George V.
Moubaraki, Boujemaa
Murray, Keith S.
Title Predesigned hexanuclear Cu II and Cu II/Ni II metallacycles featuring six-node metallacoronand structural motifs
Formatted title
Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs
Journal name Angewandte Chemie-International Edition   Check publisher's open access policy
ISSN 1433-7851
1521-3773
Publication date 2009-01
Sub-type Article (original research)
DOI 10.1002/anie.200903185
Open Access Status
Volume 48
Issue 38
Start page 7059
End page 7063
Total pages 5
Place of publication Weinheim Germany
Publisher Wiley - V C H Verlag GmbH & Co. KGaA
Language eng
Formatted abstract
Crowning glory: The assembly of CuII or CuII and NiII and a new 1,4-aryl-linked bis(triketonato) ligand designed to adopt a bent configuration leads to unusual Cu6-nNinL3 (n=0, 3) metallacycles that feature unique hexanuclear metallacoronand structural motifs. In the case of the hexanuclear CuII species, strong antiferromagnetic interactions exist between proximate pairs of metal ions in each structure.
Keyword Copper
Magnetic properties
Metallacoronands
Metallacycles
Nickel
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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