Selective anion binding by a "Chameleon" capsule with a dynamically reconfigurable exterior

Hristova, Yana R., Smulders, Maarten M. J., Clegg, Jack K., Breiner, Boris and Nitschke, Jonathan R. (2011) Selective anion binding by a "Chameleon" capsule with a dynamically reconfigurable exterior. Chemical Science, 2 4: 638-641. doi:10.1039/c0sc00495b


Author Hristova, Yana R.
Smulders, Maarten M. J.
Clegg, Jack K.
Breiner, Boris
Nitschke, Jonathan R.
Title Selective anion binding by a "Chameleon" capsule with a dynamically reconfigurable exterior
Journal name Chemical Science   Check publisher's open access policy
ISSN 2041-6520
2041-6539
Publication date 2011-01
Year available 2010
Sub-type Article (original research)
DOI 10.1039/c0sc00495b
Volume 2
Issue 4
Start page 638
End page 641
Total pages 4
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Language eng
Formatted abstract
A new class of tetrahedral metal-organic capsules that can incorporate up to twelve different externally-directed amine residues is reported, allowing for very large dynamic libraries to be formed from mixtures of amines. Selectivity is observed both externally-more electron-rich amines are incorporated in favour of electron-poor amines-and internally-PF 6- is bound in preference to CF 3SO 3- or BF 4-.
Keyword Receptor
Recognition
Complexes
Chemistry
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes First published on the web 23 December 2010.

Document type: Journal Article
Sub-type: Article (original research)
Collection: School of Chemistry and Molecular Biosciences
 
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