Syntheses, structures and spectra studies of like-scorpionate copper complexes

Wang, Xin-Yu, Xing, Na, Song, Ge, Li, Zhen, Bai, Feng-Ying and Xing, Yong-Heng (2012) Syntheses, structures and spectra studies of like-scorpionate copper complexes. Gaodeng Xuexiao Huaxue Xuebao, 33 6: 1143-1150. doi:10.3969/j.issn.0251-0790.2012.06.005

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Author Wang, Xin-Yu
Xing, Na
Song, Ge
Li, Zhen
Bai, Feng-Ying
Xing, Yong-Heng
Title Syntheses, structures and spectra studies of like-scorpionate copper complexes
Language of Title eng
Journal name Gaodeng Xuexiao Huaxue Xuebao   Check publisher's open access policy
Translated journal name Chemical Journal of Chinese Universities
Language of Journal Name chi
ISSN 0251-0790
Publication date 2012-06
Sub-type Article (original research)
DOI 10.3969/j.issn.0251-0790.2012.06.005
Volume 33
Issue 6
Start page 1143
End page 1150
Total pages 8
Place of publication Changchun, China
Publisher Jilin Daxue
Collection year 2013
Language chi
Formatted abstract
A planar tridentate pyrazole-triazine like-scorpionate compound, 2, 4-bis(3,5-dimethylpyrazol-1-yl)-6-diethylamino-1,3,5-triazine(bpz*eaT) and its two complexes [CuCl(bpz*eaT)EtOH](2)center dot(CUCl4) (1) and Cu1.5Cl3(bpz*eaT) (2) were synthesized in the organic solvent system. The complexes were characterized by elemental analysis, IR, UV and fluorescence spectra, thermogravimetric analysis, X-ray powder and X-ray single crystal diffraction technology and the structural characters of the two complexes were analyzed. The structural analysis shows that bpz*eaT is in tridentate chelated coordination mode and the coordination numbers of the center metal coppers in complexes 1 and 2 are all five, exhibiting a slightly distorted pentahedron configuration. Furthermore, the stabilities and charge distribution of the complexes were calculated by quantum chemistry.
Keyword Copper complex
Like-scorpionate ligand
Tridentate chelated coordination
Pentahedron configuration
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2013 Collection
Australian Institute for Bioengineering and Nanotechnology Publications
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