Bisiminopropadienes R-N=C=C=C=N-R from pyridopyrimidines

Andersen, Heidi Gade, Kvaskoff, David and Wentrup, Curt (2012) Bisiminopropadienes R-N=C=C=C=N-R from pyridopyrimidines. Australian Journal of Chemistry, 65 6: 686-689. doi:10.1071/CH12039


Author Andersen, Heidi Gade
Kvaskoff, David
Wentrup, Curt
Title Bisiminopropadienes R-N=C=C=C=N-R from pyridopyrimidines
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 0004-9425
1445-0038
Publication date 2012-01-01
Sub-type Article (original research)
DOI 10.1071/CH12039
Volume 65
Issue 6
Start page 686
End page 689
Total pages 4
Place of publication Collingwood, Vic., Australia
Publisher CSIRO Publishing
Collection year 2013
Language eng
Formatted abstract
Chlorination of the N,N′-di(2-pyridyl)malonamide 13a affords 2-chloro-8-methyl-4-(2-(4-picolinyl)imino-4H-pyrido[1,2-a]pyrimidine 17a. Flash vacuum thermolysis of 17a causes efficient ring opening to the valence-tautomeric ketenimine 18a/19a, elimination of HCl, and formation of the bis(4-methyl-2-pyridyl)iminopropadiene, R-N=C=C=C=N-R 20a.
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes RESEARCH FRONT: Artificial Photosynthesis: Energy, Nanochemistry, and Governance

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2013 Collection
School of Chemistry and Molecular Biosciences
 
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Created: Tue, 17 Jul 2012, 18:47:59 EST by Lucy O'Brien on behalf of School of Chemistry & Molecular Biosciences