Using NMR-based methods to assign the stereochemistry of bioactive cyclic peroxide metabolites

Yong, Ken W., Lambert, Lynette K., De Voss, James J. and Garson, Mary J. (2011). Using NMR-based methods to assign the stereochemistry of bioactive cyclic peroxide metabolites. In: NZ Institute of Chemistry Conference 2011: Book of Abstracts 2011. NZ Institute of Chemistry Conference (NZIC, 2011), Hamilton, N.Z., (91-91). 27 November-1 December 2011.

Author Yong, Ken W.
Lambert, Lynette K.
De Voss, James J.
Garson, Mary J.
Title of paper Using NMR-based methods to assign the stereochemistry of bioactive cyclic peroxide metabolites
Language of Title eng
Conference name NZ Institute of Chemistry Conference (NZIC, 2011)
Conference location Hamilton, N.Z.
Conference dates 27 November-1 December 2011
Convener NZ Institute of Chemistry
Proceedings title NZ Institute of Chemistry Conference 2011: Book of Abstracts 2011
Language of Proceedings Title eng
Language of Journal Name eng
Place of Publication Harewood, Christchurch, N.Z.
Publisher NZ Institute of Chemistry
Publication Year 2011
Year available 2011
Sub-type Published abstract
Start page 91
End page 91
Total pages 1
Collection year 2012
Language eng
Formatted Abstract/Summary
This talk describes the metabolite-rich extract of the Australian sponge Plakinastrella clathrata Kirkpatrick, 1900.

An enantioselective HPLC study compared natural plakortoperoxide A with a synthetic sample prepared by cyclization of plakortolide P with singlet oxygen, and revealed that the natural sample was a mixture of syn diastereomers at C-15/C18.
Q-Index Code EX
Q-Index Status Provisional Code
Institutional Status UQ

 
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Created: Fri, 02 Mar 2012, 15:12:37 EST by Lucy O'Brien on behalf of School of Chemistry & Molecular Biosciences