Confirmation of the classic tris(2,20-bipyridyl)ruthenium(II) and oxalate electrochemiluminescence mechanism using EPR spectroscopy

Hindson, Christopher M., Francis, Paul S., Hanson, Graeme R. and Barnett, Neil W. (2011) Confirmation of the classic tris(2,20-bipyridyl)ruthenium(II) and oxalate electrochemiluminescence mechanism using EPR spectroscopy. Chemical Communications, 2011 47: 7806-7808. doi:10.1039/C1CC11434D


Author Hindson, Christopher M.
Francis, Paul S.
Hanson, Graeme R.
Barnett, Neil W.
Title Confirmation of the classic tris(2,20-bipyridyl)ruthenium(II) and oxalate electrochemiluminescence mechanism using EPR spectroscopy
Journal name Chemical Communications   Check publisher's open access policy
ISSN 1359-7345
1364-548X
Publication date 2011-01-01
Sub-type Article (original research)
DOI 10.1039/C1CC11434D
Volume 2011
Issue 47
Start page 7806
End page 7808
Total pages 3
Place of publication Cambridge, U.K.
Publisher Royal Society of Chemistry
Collection year 2012
Language eng
Formatted abstract
A chemically initiated adaptation of the classic [Ru(bipy)3]2+/ oxalate electrochemiluminescence coreactant system has revealed the elusive radical intermediates of the light-producing pathway. Oxalyl (HC2O4˙) and hydroxyformyl (HCO2˙) radicals have been captured on a quartz surface and characterised using EPR spectroscopy.
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2012 Collection
Centre for Advanced Imaging Publications
 
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Created: Wed, 07 Sep 2011, 22:30:23 EST by Sandrine Ducrot on behalf of Centre for Advanced Imaging