Any old radical won't do: An EPR study of the selective excitation and quenching mechanisms of [Ru(bipy)3]2+ chemiluminescence and electrochemiluminescence

Hindson, Christopher M., Hanson, Graeme R., Francis, Paul S., Adcock, Jacqui L. and Barnett, Neil W. (2011) Any old radical won't do: An EPR study of the selective excitation and quenching mechanisms of [Ru(bipy)3]2+ chemiluminescence and electrochemiluminescence. Chemistry - A European Journal, 17 29: 8018-8022. doi:10.1002/chem.201100877


Author Hindson, Christopher M.
Hanson, Graeme R.
Francis, Paul S.
Adcock, Jacqui L.
Barnett, Neil W.
Title Any old radical won't do: An EPR study of the selective excitation and quenching mechanisms of [Ru(bipy)3]2+ chemiluminescence and electrochemiluminescence
Formatted title
Any old radical won't do: An EPR study of the selective excitation and quenching mechanisms of [Ru(bipy)3]2+ chemiluminescence and electrochemiluminescence
Journal name Chemistry - A European Journal   Check publisher's open access policy
ISSN 0947-6539
1521-3765
Publication date 2011-07-11
Sub-type Article (original research)
DOI 10.1002/chem.201100877
Volume 17
Issue 29
Start page 8018
End page 8022
Total pages 5
Place of publication Weinheim, Germany
Publisher Wiley - VCH Verlag
Collection year 2012
Language eng
Formatted abstract
[Ru(bipy)3]2+ chemiluminescence: The mechanisms governing the selectivity of the luminescence of the [Ru(bipy)3] 2+ complex (bipy=2,2′-bipyridyl) were investigated using continuous flow EPR spectroscopy. The radical intermediates of substrates thought to evoke or quench the emission from this reagent were characterized in the light-producing pathway.
Keyword Density functional calculations
Electrochemiluminescence
EPR spectroscopy
Luminescence
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2012 Collection
Centre for Advanced Imaging Publications
 
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Created: Wed, 24 Aug 2011, 16:34:09 EST by Sandrine Ducrot on behalf of Centre for Advanced Imaging