Practical synthesis and reactivity of [3]dendralene

Bradford, TA, Payne, AD, Willis, AC, Paddon-Row, MN and Sherburn, MS (2010) Practical synthesis and reactivity of [3]dendralene. Journal of Organic Chemistry, 75 2: 491-494. doi:10.1021/jo9024557


Author Bradford, TA
Payne, AD
Willis, AC
Paddon-Row, MN
Sherburn, MS
Title Practical synthesis and reactivity of [3]dendralene
Journal name Journal of Organic Chemistry   Check publisher's open access policy
ISSN 0022-3263
Publication date 2010-01
Sub-type Article (original research)
DOI 10.1021/jo9024557
Volume 75
Issue 2
Start page 491
End page 494
Total pages 4
Place of publication United States
Publisher American Chemical Society
Collection year 2012
Language eng
Abstract (Chemical Equation Presented) Aconvenient and high-yielding three-step synthesis of the simplest branched triene, [3]dendralene, has been devised. The synthesis is robust and operationally simple, requiring no chromatography and involving no protecting groups or specialized equipment, allowing the synthesis of the volatile hydrocarbon in pure, solvent free form on a multigram scale. The stability, dimerization when stored neat, and Diels-Alder reactivity of [3]dendralene - including double cycloaddition sequences and catalytic enantioselective variant - are reported. © 2009 American Chemical Society.
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Non HERDC
Institute for Molecular Bioscience - Publications
 
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Citation counts: TR Web of Science Citation Count  Cited 31 times in Thomson Reuters Web of Science Article | Citations
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Created: Fri, 17 Jun 2011, 13:52:00 EST by Ms Tanya Bradford on behalf of Institute for Molecular Bioscience