Improved method for fitting falloff data

Poole, James S. and Gilbert, Robert G. (1994) Improved method for fitting falloff data. International Journal of Chemical Kinetics, 26 2: 273-281. doi:10.1002/kin.550260205

Author Poole, James S.
Gilbert, Robert G.
Title Improved method for fitting falloff data
Journal name International Journal of Chemical Kinetics   Check publisher's open access policy
ISSN 0538-8066
Publication date 1994-02
Sub-type Article (original research)
DOI 10.1002/kin.550260205
Volume 26
Issue 2
Start page 273
End page 281
Total pages 9
Place of publication Hoboken, NJ, United States
Publisher John Wiley & Sons
Language eng
Abstract An extension of the dimensionless treatment of Troe is developed for fitting falloff data from unimolecular and recombination reactions. This method using dimensionless parameterizations derived from accurate numerical solutions of the master equation for system with any type of activated complex and energy transfer probability distribution, is as easily implemented as Troe's method, and allows global fitting of an entire set of pressure and temperature-dependant rate coefficients.
Keyword Thermal unimolecular reactions
Angular-momentum conservation
Collision rate constants
Rate coefficients
Multiphoton ionization
General expression
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes Article first published online: 30 September 2004.

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Chemistry and Molecular Biosciences
Centre for Nutrition and Food Sciences Publications
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Citation counts: TR Web of Science Citation Count  Cited 9 times in Thomson Reuters Web of Science Article | Citations
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Created: Mon, 07 Mar 2011, 15:55:56 EST