Prediction of the rate coefficient for the F+SOF3 recombination reaction

Pitt, I. G., Gilbert, R. G. and Ryan, K. R. (1990) Prediction of the rate coefficient for the F+SOF3 recombination reaction. Australian Journal of Chemistry, 43 1: 169-178.


Author Pitt, I. G.
Gilbert, R. G.
Ryan, K. R.
Title Prediction of the rate coefficient for the F+SOF3 recombination reaction
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 0004-9425
Publication date 1990-01-01
Sub-type Article (original research)
Volume 43
Issue 1
Start page 169
End page 178
Total pages 10
Place of publication Collingwood, VIC, Australia
Publisher CSIRO
Language eng
Abstract The pressure dependence of the rate coefficient for the recombination reaction SOF3+F → SOF4 has been calculated by utilizing an RRKM canonical variational approach with a hindered-rotor Gorin potential surface. With no adjustable parameters, the high-pressure recombination rate coefficient is predicted to be c. 1×10-10cm3s-1. It was further established that this rate coefficient is close to its high-pressure limit above c. 100 Pa. These results support the conclusions of an experimental study in which this rate coefficient was measured relative to that of the association reaction between SOF3 and O.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Centre for Nutrition and Food Sciences Publications
 
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Created: Tue, 08 Mar 2011, 01:55:26 EST