Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents

vandenAncker, Tania R., Hanson, Graeme R., Lee, Fu-Chin and Raston, Colin L. (1997) Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents. Chemical Communications, 1: 125-126. doi:10.1039/a606181h


Author vandenAncker, Tania R.
Hanson, Graeme R.
Lee, Fu-Chin
Raston, Colin L.
Title Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents
Journal name Chemical Communications   Check publisher's open access policy
ISSN 1359-7345
1364-548X
Publication date 1997-01
Sub-type Article (original research)
DOI 10.1039/a606181h
Issue 1
Start page 125
End page 126
Total pages 2
Place of publication Cambridge, England
Publisher Royal Society of Chemistry
Language eng
Subject 030606 Structural Chemistry and Spectroscopy
030207 Transition Metal Chemistry
Formatted abstract
Polymer supported lithium and sodium naphthalenide complexes are prepared from the reaction of THF solutions of lithium and sodium biphenylide with polystyrene bearing -CH2SiMe2(1-C10H7) groups, generating highly coloured paramagnetic material, which afford lithium and sodium reagents in high yield when treated with organic halides, nitriles and phosphates.
Keyword DTBB-catalyzed lithiation
Direct transformation
Barrier-type
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Centre for Advanced Imaging Publications
 
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