Amidoalkylation of Phosphorus Trichloride with Acetamide and Alkyl Oxocycloalkanecarboxylates

Ziora, Zyta and Kafarski, Pawel (2009) Amidoalkylation of Phosphorus Trichloride with Acetamide and Alkyl Oxocycloalkanecarboxylates. Phosphorus, Sulfur, and Silicon and the Related Elements, 184 4: 1047-1053. doi:10.1080/10426500902737356


Author Ziora, Zyta
Kafarski, Pawel
Title Amidoalkylation of Phosphorus Trichloride with Acetamide and Alkyl Oxocycloalkanecarboxylates
Journal name Phosphorus, Sulfur, and Silicon and the Related Elements   Check publisher's open access policy
ISSN 1042-6507
Publication date 2009-04
Year available 2009
Sub-type Article (original research)
DOI 10.1080/10426500902737356
Volume 184
Issue 4
Start page 1047
End page 1053
Total pages 7
Editor Robert R. Holmes
Place of publication United States
Publisher Taylor & Francis
Language eng
Abstract Abstracting & Indexing Online Submissions Related Websites General Information Permissions Information Reprints iOpen Amidoalkylation of Phosphorus Trichloride with Acetamide and Alkyl Oxocycloalkanecarboxylates Authors: Zyta Ziora a;Pawelstrok Kafarski a Affiliation: a Department of Bioorganic Chemistry, Faculty of Chemistry, Technical University of Wroclstrokaw, Wroclstrokaw, Poland DOI: 10.1080/10426500902737356 Publication Frequency: 12 issues per year Published in: journal Phosphorus, Sulfur, and Silicon and the Related Elements, Volume 184, Issue 4 April 2009 , pages 1047 - 1053 Subjects: Inorganic Chemistry; Materials Chemistry; Organic Chemistry; Formats available: HTML (English) : PDF (English) You have: ACCESS ACCESS Previously published as: Phosphorous and Sulfur and the Related Elements (0308-664X) until 1989 Article Requests: Order Reprints : Request Permissions View Article: View Article (PDF) View Article (PDF) View Article (HTML) View Article (HTML) Abstract The course of the reaction between phosphorus trichloride, acetamide, and ethyl oxoalkanecarboxylates was studied in terms of the production of side-products. When alkyl 2-oxocycloalkanecarboxylates were used as substrates, together with the expected products—2-amino-2-phosphonocycloalkanecarboxylic acids—three side-products, namely 1-aminocycloalkanephosphonic acids (decarboxylation products of the latter compounds), 1-aminoethane-1,1-diphosphonic acids, and 1-hydroxyethane-1,1-diphosphonic acids were identified. Ethyl 1-oxocycloalkanecarboxylate afforded 4-amino-4-phosphonocyclohexane carboxylic acid in good yield. Copyright Taylor & Francis Group, LLC
Keyword Aminophosphonates
analogs of aspartic and glutamic acids
Oleksyszyn-Soroka reaction
Q-Index Code C1
Q-Index Status Provisional Code

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Chemistry and Molecular Biosciences
Centre for Integrated Preclinical Drug Development Publications
 
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Citation counts: TR Web of Science Citation Count  Cited 3 times in Thomson Reuters Web of Science Article | Citations
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Created: Thu, 15 Apr 2010, 13:56:20 EST by Barb Clyde on behalf of Centre for Integrated Preclinical Drug Development