An Efficient and Solvent-Free Synthesis of Mixed Ortho Esters

Cosgrove, Kelly L. and McGeary, Ross P. (2008) An Efficient and Solvent-Free Synthesis of Mixed Ortho Esters. Synlett, 2008 16: 2425-2428. doi:10.1055/s-2008-1078215

Author Cosgrove, Kelly L.
McGeary, Ross P.
Title An Efficient and Solvent-Free Synthesis of Mixed Ortho Esters
Journal name Synlett   Check publisher's open access policy
ISSN 0936-5214
Publication date 2008-10
Sub-type Article (original research)
DOI 10.1055/s-2008-1078215
Volume 2008
Issue 16
Start page 2425
End page 2428
Total pages 4
Place of publication Stuttgart, Germany
Publisher Georg Thieme Verlag
Collection year 2009
Language eng
Subject C1
030503 Organic Chemical Synthesis
970103 Expanding Knowledge in the Chemical Sciences
Formatted abstract
Primary, secondary and electron-deficient tertiary alcohols react rapidly with ketene dimethyl acetal to form mixed ortho esters, without catalysts and under solvent-free conditions. 1,2-Diols yield bis(mixed ortho esters), rather than cyclic ortho esters.
Keyword ortho esters
ketene dimethyl acetal
Q-Index Code C1
Q-Index Status Confirmed Code
Additional Notes Letter.

Document type: Journal Article
Sub-type: Article (original research)
Collections: 2009 Higher Education Research Data Collection
School of Chemistry and Molecular Biosciences
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Citation counts: TR Web of Science Citation Count  Cited 3 times in Thomson Reuters Web of Science Article | Citations
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Created: Mon, 09 Mar 2009, 10:43:16 EST by Jennifer Falknau on behalf of School of Chemistry & Molecular Biosciences