Bis{methyl [1-(6-acetyl-2-pyridyl)ethylidene]hydrazinecarbodithioato}nickel(II)

Ali, Mohammad Akbar, Mirza, Aminul Huq and Bernhardt, Paul V. (2007) Bis{methyl [1-(6-acetyl-2-pyridyl)ethylidene]hydrazinecarbodithioato}nickel(II). Acta Crystallographica Section E: Structure Reports Online, 63 9: m2255-m2255. doi:10.1107/S1600536807037129

Author Ali, Mohammad Akbar
Mirza, Aminul Huq
Bernhardt, Paul V.
Title Bis{methyl [1-(6-acetyl-2-pyridyl)ethylidene]hydrazinecarbodithioato}nickel(II)
Journal name Acta Crystallographica Section E: Structure Reports Online   Check publisher's open access policy
ISSN 1600-5368
Publication date 2007-09
Year available 2007
Sub-type Article (original research)
DOI 10.1107/S1600536807037129
Open Access Status DOI
Volume 63
Issue 9
Start page m2255
End page m2255
Total pages 1
Place of publication Malden, MA, U.S.A.
Publisher Wiley-Blackwell Publishing
Collection year 2008
Language eng
Subject 250105 Structural Chemistry
780103 Chemical sciences
Formatted abstract
The title compound, [Ni(C11H12N3OS2)2], is a six-coordinate NiII complex that is similar to other bis-tridentate N,N′,S-coordinated Schiff bases, but in this case an acetyl substituent adjacent to the coordinated pyridyl N atom elongates the Ni-N bond by more than 0.06 Å relative to the complex where no substituent is present. A related 6-methyl-substituted Ni complex also shows a similar Ni-N bond elongation.
Keyword Crystallography
Ray crystal-structure
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

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Created: Mon, 18 Feb 2008, 15:11:58 EST