A functionalised macrobicycle complex available for surface immobilisation and protein grafting

Bernhardt, Paul V., Harrowfield, Jack M., Kim, Yang, Lee, Young Hoon, Park, Yu Cheol and Sujandi (2007) A functionalised macrobicycle complex available for surface immobilisation and protein grafting. Bulletin of The Korean Chemical Society, 28 4: 589-595. doi:10.5012/bkcs.2007.28.4.589


Author Bernhardt, Paul V.
Harrowfield, Jack M.
Kim, Yang
Lee, Young Hoon
Park, Yu Cheol
Sujandi
Title A functionalised macrobicycle complex available for surface immobilisation and protein grafting
Journal name Bulletin of The Korean Chemical Society   Check publisher's open access policy
ISSN 0253-2964
1229-5949
Publication date 2007-04
Sub-type Article (original research)
DOI 10.5012/bkcs.2007.28.4.589
Open Access Status DOI
Volume 28
Issue 4
Start page 589
End page 595
Total pages 7
Place of publication Seoul, Republic of Korea
Publisher Korean Chemical Society
Collection year 2008
Language eng
Subject C1
780103 Chemical sciences
250201 Transition Metal Chemistry
Formatted abstract
The conversion of both the racemic and resolved forms of the Co(III) complex of an hydroxymethyl-substituted tripodal hexamine to inacrobicycles via reaction with formaldehyde and nitromethane (and subsequent reduction of the product) has been conducted. The prospect is that it will provide cage complexes in which the hydroxyl substituent is sufficiently remote from the metal ion centre for its nucelophilicity to be largely unaffected. X-ray structure determinations have been used to characterise these new cage species as well as some complexes of the precursor hexamine and its mono-aminal. The electrochemistry and optical activity of the complexes have also been studied in detail.
Keyword Chemistry, Multidisciplinary
Macrocycle
Co(III)
Cage
Hexamine
Electrochemistry
Cobalt(iii) Cage Complexes
Electron-transfer
Metal-ions
Agents
Azamacrocycles
Coordination
Amines
Ligand
Sarar
State
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

 
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Created: Mon, 18 Feb 2008, 17:19:11 EST